SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.055M) Thu Feb 25 08:43:14 2021 No. of days remaining = 364 Empirical Formula: Zr36 = 36 atoms LET RELSCF=10 MERS=(2,3,3) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Zirconium (Zr) (ICSD 653525) hcp h=0 hr=element GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = 1583.78367 KCAL/MOL = 6626.55086 KJ/MOL H.o.F. per unit cell = 43.99399 KCAL, for 36 unit cells, unit cell = Zr1 TOTAL ENERGY = -2103.55677 EV ELECTRONIC ENERGY = -8699738.69038 EV CORE-CORE REPULSION = 8697635.13362 EV VOLUME OF UNIT CELL = 41.257 CUBIC ANGSTROMS DENSITY = 7.343 GRAMS/CC A = 4.913 ANGSTROMS B = 3.118 ANGSTROMS C = 3.110 ANGSTROMS ALPHA = 120.009 DEGREES BETA = 89.982 DEGREES GAMMA = 90.116 DEGREES VOLUME OF CLUSTER = 742.63063 ANGSTROMS**3 = 447.222 CM**3/MOLE GRADIENT NORM = 4.04885 = 0.67481 PER ATOM NO. OF FILLED LEVELS = 72 IONIZATION POTENTIAL = 4.510130 EV HOMO LUMO ENERGIES (EV) = -4.510 -1.260 MOLECULAR WEIGHT = 3283.9200 Pressure required to constrain translation vectors Tv( 37) Pressure: -0.07 GPa Tv( 38) Pressure: -0.06 GPa Tv( 39) Pressure: 0.10 GPa SCF CALCULATIONS = 19 WALL-CLOCK TIME = 21 MINUTES AND 25.838 SECONDS COMPUTATION TIME = 21 MINUTES AND 2.052 SECONDS FINAL GEOMETRY OBTAINED LET RELSCF=10 MERS=(2,3,3) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Zirconium (Zr) (ICSD 653525) hcp h=0 hr=element Zr 0.22641108 +1 0.15729004 +1 -0.18303066 +1 Zr 3.22317422 +1 -0.00165568 +1 -0.15064344 +1 Zr 4.09272971 +1 2.88272791 +1 -0.05878015 +1 Zr 7.18669056 +1 2.98083559 +1 -0.06954381 +1 Zr -1.45115708 +1 2.19107292 +1 -1.65701396 +1 Zr 1.66893675 +1 2.36105227 +1 -1.72455220 +1 Zr 2.61637472 +1 5.25504000 +1 -1.68769606 +1 Zr 5.59145327 +1 5.00663012 +1 -1.64872188 +1 Zr -3.02205072 +1 4.52770422 +1 -3.19546932 +1 Zr -0.01326004 +1 4.42868623 +1 -3.14746397 +1 Zr 1.02727254 +1 7.30926952 +1 -3.26630804 +1 Zr 4.10600986 +1 7.35792880 +1 -3.29850179 +1 Zr 1.68015849 +1 -2.19693424 +1 -1.66591396 +1 Zr 4.81177106 +1 -2.02336320 +1 -1.72500532 +1 Zr 5.76525781 +1 0.87463030 +1 -1.69541311 +1 Zr 8.73966659 +1 0.61629692 +1 -1.65595140 +1 Zr 0.12190172 +1 0.14223074 +1 -3.19846904 +1 Zr 3.13380979 +1 0.03176956 +1 -3.16695100 +1 Zr 4.17219157 +1 2.92321469 +1 -3.28235120 +1 Zr 7.24524243 +1 2.97481666 +1 -3.31687836 +1 Zr -1.35383730 +1 2.36318765 +1 -4.84692761 +1 Zr 1.64244066 +1 2.19712109 +1 -4.81861643 +1 Zr 2.50404151 +1 5.08619736 +1 -4.71822379 +1 Zr 5.60047476 +1 5.18248180 +1 -4.74251974 +1 Zr 3.26833976 +1 -4.24763047 +1 -3.20675398 +1 Zr 6.27909439 +1 -4.35036619 +1 -3.16464135 +1 Zr 7.31722907 +1 -1.46623079 +1 -3.29859418 +1 Zr 10.38669377 +1 -1.41528949 +1 -3.31233591 +1 Zr 1.79050321 +1 -2.03340136 +1 -4.86552862 +1 Zr 4.78410994 +1 -2.18844605 +1 -4.82396735 +1 Zr 5.64431843 +1 0.70264360 +1 -4.73566343 +1 Zr 8.74687270 +1 0.79685739 +1 -4.75697406 +1 Zr 0.09351675 +1 0.00615547 +1 -6.32357740 +1 Zr 3.21347954 +1 0.17558445 +1 -6.39227551 +1 Zr 4.18290682 +1 3.07225703 +1 -6.36192998 +1 Zr 7.15900568 +1 2.82524205 +1 -6.32118099 +1 Tv 7.99586105 +1 5.71267482 +1 0.00303491 +1 Tv -4.72872132 +1 6.58843717 +1 -4.66173450 +1 Tv 4.69581438 +1 -6.56497823 +1 -4.67877901 +1